赵万祥，湖南大学化学化工学院副院长，化学生物传感与计量学国家重点实验室教授、博士生导师，2017年入选第13批海外高层次人才计划。2014年博士毕业于香港科技大学，2014-2017先后在密歇根大学（安娜堡分校）John Montgomery教授课题组和犹他大学JACS主编Peter Stang教授课题组从事博士后，以通讯作者和第一作者在Nat. Chem.,J. Am. Chem. Soc，Angew. Chem. Int. Ed等期刊发表高水平论文40余篇。

2017.03-至今 湖南大学化学化工学院

2016.03-2017.03 犹他大学（博士后合作导师：Peter Stang）

2014.02-2016.02 密歇根大学安娜堡分校（博士后合作导师：John Montgomery）

2011.02-2014.02 博士研究生 香港科技大学（导师：孙建伟教授）

2007.09-2010.07 硕士研究生 华东师范大学（导师：张俊良教授）

发表论文：

[1]Asymmetric Dihydroboration of Allenes Enabled by Ligand Relay Catalysis Yaqin Lei, Yu Kong, Zi-Qiang Rong,* andWanxiang Zhao*,Nat. Commun.(Accepted)

[2]Catalytic Contra-Thermodynamic Asymmetric

Isomerization/Hydroboration of Alkenyl Alcohols and Amines

Chenchen Li, Kezhuo Zhang, andWanxiang Zhao*,ACS Catalysis  2024, 14, 3977-3985. 

[3]Enantio- and Regioselective Dihydroboration of Enals Kezhuo Zhang, Chenchen Li, andWanxiang Zhao*,ACS Catalysis  2024, 14, 3977-3985.

[4]Mixed Valence BN-Doped Corannulene Trimer Radical Cations Yapei Gao, Zheming Liu, Tao Li*, andWanxiang Zhao*,Angew. Chem. Int. Ed.2023,62, e202314006.

[5]Cobalt-Catalyzed Asymmetric Remote Borylation of Alkyl Halides

Minghao Zhang,#Zhiyang Ye,#andWanxiang Zhao*,Angew. Chem. Int. Ed.2023,62,e202306248.

[6]Rhodium-Catalyzed Remote Borylation of Alkynes and Vinylboronates Minghao Zhang, Zheming Liu, andWanxiang Zhao*,Angew. Chem. Int. Ed.2023,62,e202215455.

[7]Asymmetric Oxidative Lactonization of Enynyl Boronates Kezhuo Zhang#, Chenchen Li#, Yining Jia, andWanxiang Zhao*,Angew. Chem. Int. Ed.2022,61,e202209004.

[8]Enantioselective Cobalt-Catalyzed Hydroboration of Ketone-Derived Silyl Enol Ethers Wenke Dong, Zhiyang Ye, andWanxiang Zhao*,Angew. Chem. Int. Ed.2022,61,e2021174

[9]Rhodium-Catalyzed Regioselective and Chemoselective Deoxygenative Reduction of 1,3-DiketonesBing Zhang,§Xueying Guo,§Lei Tao, Ruolin Li, Zhenyang Lin,* andWanxiang Zhao*,ACS Catal. 2022, 12, 4640-4647.

[10]Enantioselective Rh-Catalyzed Hydroboration of Silyl Enol EthersWenke Dong,#Xin Xu,#Honghui Ma, Yaqin Lei, Zhenyang Lin, andWanxiang Zhao*,J. Am. Chem. Soc.2021,143, 10902-10909.

[11]Rhodium-Catalyzed Regiodivergent Synthesis of Alkylboronates via Deoxygenative Hydroboration of Aryl Ketones: Mechanism and Origin of SelectivitiesBing Zhang,§Xin Xu,§Lei Tao, Zhenyang Lin,* andWanxiang Zhao*,ACS Catal.2021,11, 9495-9505.

[12]Stereodefined tetraarylethylenes: Synthesis and applications

Minghao ZhangandWanxiang Zhao*,Aggregate.2021;2:e60.

[13]Rhodium-Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical InvestigationLei Tao,∇Xueying Guo,∇Jie Li, Ruoling Li, Zhenyang Lin,* andWanxiang Zhao*,J. Am. Chem. Soc.2020,142, 18118-18127.

[14]Divergent and Stereoselective Synthesis of Tetraarylethylenes from VinylboronatesMinghao Zhang,Yisen Yao,Peter J. Stang*andWanxiang Zhao*,Angew. Chem. Int. Ed.2020,59, 20090-20098.

[15]Oxidation of Alkynyl Boronates to Carboxylic Acids, Esters and AmidesChenchen Li, Pei Zhao, Ruoling Li, Bing Zhang, andWanxiang Zhao*,Angew. Chem. Int. Ed.2020,59,10913-10917.

[16]Rhodium‐Catalyzed Remote C(sp3)−H Borylation of Silyl Enol EthersJieLi, Shuanglin Qu, andWanxiang Zhao*,Angew. Chem. Int. Ed.2020, 59,2360-2364.

[17]Formation of a Supramolecular Polymeric Adhesive via Water-Participant Hydrogen Bonding FormationQiao Zhang,⊥Tao Li,⊥Abing Duan,⊥Shengyi Dong,*Wanxiang Zhao,* and Peter J. Stang*,J. Am. Chem. Soc.2019,141, 8058-8063.

[18]Triflimide (HNTf2) in Organic SynthesisWanxiang Zhaoand Jianwei Sun*,Chem. Rev.2018,118, 10349-10392.

独立工作前代表性论文：

[1]Zhao, W.; Montgomery, J.* Cascade Copper-Catalyzed 1,2,3-Trifunctionalization of Terminal AllenesJ. Am. Chem. Soc.2016,138, 9763-9766.

[2] Zhao, W.; Montgomery, J.* Functionalization of Styrenes via Copper-Catalyzed Borylation/ortho-Cyanation and Silver-Catalyzed Annulation ProcessesAngew. Chem. Int. Ed.2015,54, 12683-12683.

[3]Zhao, W.; Wang, Z.; Chu, B.; Sun, J*. Enantioselective Formation of All-Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing GroupAngew. Chem. Int. Ed.2015,54, 1910-1913 (Highlighted in SynFact)

[4]Zhao, W.; Qian, H.; Li, Z*.; Sun, J.* Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium Ring LactamsAngew. Chem. Int. Ed.2015,54, 10005-10008.

[5]Zhao, W.; Li, Z.; Sun, J*. A New Strategy for Efficient Synthesis of Medium and Large Ring Lactones without High Dilution or Slow AdditionJ. Am. Chem. Soc.2013,135, 4680-4683.

[6]Zhao, W.; Wang, Z.; Sun, J*. Synthesis of 8-Membered Lactones via Intermolecular [6+2] Cyclization of New Amphoteric Molecules with Siloxy Alkynes.Angew. Chem. Int. Ed.2012,51, 6209-6213.

[1]海外高层次人才引进计划